Functionalized Chiral Ionic Liquids: A New Type of Asymmetric Organocatalysts and Nonclassical Chiral Ligands

被引：85

作者：

Luo, Sanzhong ^{[1
]}

Zhang, Long ^{[1
]}

Cheng, Jin-Pei ^{[2
,3
]}

机构：

[1] Chinese Acad Sci, Ctr Chem Biol, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China

[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[3] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2009年 / 4卷 / 08期

关键词：

asymmetric catalysis; chiral ligands; functionalization; ionic liquids; organocatalysis; NUCLEOPHILIC-SUBSTITUTION REACTIONS; ENANTIOSELECTIVE MICHAEL ADDITION; BAYLIS-HILLMAN REACTION; DIELS-ALDER REACTIONS; AMINO-ACID; ROOM-TEMPERATURE; HIGHLY EFFICIENT; SUPPORTED ORGANOCATALYST; IMIDAZOLINIUM SALTS; ALDOL REACTION;

D O I：

10.1002/asia.200900080

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By judiciously anchoring functional groups onto chiral ionic liquids, functionalized chiral ionic liquids (FCILs) are emerging as a new type of asymmetric organocatalysts and nonclassical chiral ligands. This Focus Review highlights the applications of FCILs from the viewpoint of asymmetric catalysis. We focus mainly on the de novo designed and synthesized FCILs which likely still maintain the typical ionic liquids properties, and in a few cases relevant ionic liquid immobilized chiral catalysts are briefly discussed.

引用

页码：1184 / 1195

页数：12

共 148 条

[1] Supported choline hydroxide (ionic liquid) as heterogeneous catalyst for aldol condensation reactions [J].