The peroxy radical ammonia complex. A matrix isolation study

被引：17

作者：

Engdahl, A ^{[1
]}

Nelander, B ^{[1
]}

机构：

[1] Univ Lund, Div Phys Chem, Chem Ctr Chem & Chem Engn, S-22100 Lund, Sweden

来源：

CHEMICAL PHYSICS | 1999年 / 249卷 / 2-3期

关键词：

peroxy radical ammonia complex; infrared spectrum; matrix isolation method;

D O I：

10.1016/S0301-0104(99)00267-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared spectrum of the peroxy radical ammonia complex in argon matrices has been measured between 200 and 4000 cm(-1) for several ammonia and peroxy radical isotopomers. The shifts of the intramolecular fundamentals indicate that the peroxy radical forms a strong hydrogen bond to the lone pair of the ammonia nitrogen. The H- to D-shift of the OH stretch of the complexed peroxy radical indicates a significant weakening of the OH bond. (C) 1999 Elsevier Science B.V. All lights reserved.

引用

页码：215 / 221

页数：7

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