Thermal and light induced polymorphism in iron(II) spin crossover compounds

被引：103

作者：

Thompson, AL

Goeta, AE

Real, JA

Galet, A

Muñoz, MC

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Valencia, Dept Quim Inorgan, Inst Ciencia Mol, Burjassot, Spain

[3] Univ Politecn Valencia, Dept Fis Aplicada, Valencia, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 12期

关键词：

D O I：

10.1039/b403179b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The spin crossover complexes (Fe[H2B(PZ)(2)](2)L) ([H2B(pz)(2)](-) = dihydrobis(pyrazolyl)borate, L = 2,2'-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for 2 are different from that of the thermally induced high spin state and from those of 1.

引用

页码：1390 / 1391

页数：2

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