C-S bond cleavage routes to the titanium-sulfide complexes (CpTi)(6)(mu(3)-S)(4)(mu(3)-O)(4) and (CpTi)(4)(mu(3)-S)(3)(mu(2)-S)(mu(2)-SEt)(2) (Cp=eta-C5H5)

被引：16

作者：

Firth, AV ^{[1
]}

Stephan, DW ^{[1
]}

机构：

[1] UNIV WINDSOR, DEPT CHEM & BIOCHEM, WINDSOR, ON N9B 3P4, CANADA

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 06期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1021/ic961520r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis at 80 degrees C of reaction mixtures of CpTiMeCl(2), thiol, and base results in C-S bond cleavage and the isolation of two new Ti-sulfide species (CPTi)(4)(mu(3)-S)(3)(mu(2)-S)(mu(2)-SEt)(2) and (CpTi)(6-) (mu(3)-S)(4)(mu(3)-O)(4) (Cp = eta-C5H5), both of which have been crystallographically characterized. (Cp ligands are omitted from the diagram.)

引用

页码：1260 / +

页数：4

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