In situ diagnostic techniques for characterisation of polymer electrolyte membrane water electrolysers - Flow visualisation and electrochemical impedance spectroscopy

被引：166

作者：

Dedigama, I. ^{[1
]}

Angeli, P. ^{[1
]}

Ayers, K. ^{[2
]}

Robinson, J. B. ^{[1
]}

Shearing, P. R. ^{[1
]}

Tsaoulidis, D. ^{[1
]}

Brett, D. J. L. ^{[1
]}

机构：

[1] UCL, Dept Chem Engn, Electrochem Innovat Lab, London, England

[2] Proton OnSite, Wallingford, CT USA

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2014年 / 39卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

PEM electrolyser; Electrochemical impedance spectroscopy; Two-phase flow; Bubble formation; Thermal imaging; Printed circuit board; FUEL-CELL RESEARCH; HYDROGEN GENERATION; 2-PHASE FLOW; EVOLUTION REACTION; OXYGEN EVOLUTION; ELECTROCATALYSIS; METHANOL; TECHNOLOGY; CORROSION; CHANNEL;

D O I：

10.1016/j.ijhydene.2014.01.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

An optically transparent polymer electrolyte membrane (PEM) water electrolysis cell was studied using a high-speed camera, thermal imaging and electrochemical impedance spectroscopy to examine the relationship between flow and electrochemical performance. The flow regime spans bubble and slug flow, depending on the rate of gas formation (current density) and water feed rate. Electrochemical impedance spectroscopy (EIS) shows that there is a reduction in mass transport limitation associated with the transition to slug flow. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：4468 / 4482

页数：15

共 63 条

[1]

Alvensleben DLv PHYWE, EXPT LIT LAB EXPT

[2]

SOLID POLYMER ELECTROLYTE WATER ELECTROLYSIS - ELECTROCATALYSIS AND LONG-TERM STABILITY [J].

ANDOLFATTO, F ;

DURAND, R ;

MICHAS, A ;

MILLET, P ;

STEVENS, P .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1994, 19 (05) :421-427

[3]

[Anonymous], 1960, Transport Phenomena

[4]

[Anonymous], 2017, HYDR EN FUEL CELLS V

[5]

PEM electrolysis for production of hydrogen from renewable energy sources [J].

Barbir, F .

SOLAR ENERGY, 2005, 78 (05) :661-669

[6]

Liquid water visualization in PEM fuel cells: A review [J].

Bazylak, A. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (09) :3845-3857

[7]

Novel method for investigation of two-phase flow in liquid feed direct methanol fuel cells using an aqueous H2O2 solution [J].

Bewer, T ;

Beckmann, T ;

Dohle, H ;

Mergel, J ;

Stolten, D .

JOURNAL OF POWER SOURCES, 2004, 125 (01) :1-9

[8]

Membrane resistance and current distribution measurements under various operating conditions in a polymer electrolyte fuel cell [J].

Brett, D. J. L. ;

Atkins, S. ;

Brandon, N. P. ;

Vasileiadis, N. ;

Vesovic, V. ;

Kucernak, A. R. .

JOURNAL OF POWER SOURCES, 2007, 172 (01) :2-13

[9]

Measurement of the current distribution along a single flow channel of a solid polymer fuel cell [J].

Brett, DJL ;

Atkins, S ;

Brandon, NP ;

Vesovic, V ;

Vasileiadis, N ;

Kucernak, AR .

ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (11) :628-632

[10]

A simple model for solid polymer electrolyte (SPE) water electrolysis [J].

Choi, PH ;

Bessarabov, DG ;

Datta, R .

SOLID STATE IONICS, 2004, 175 (1-4) :535-539

← 1 2 3 4 5 6 7 →