Reduction of azides to amines mediated by tin bis(1,2-benzenedithiolate)

被引：31

作者：

Bosch, I ^{[1
]}

Costa, AM ^{[1
]}

Martín, M ^{[1
]}

Urpí, F ^{[1
]}

Vilarrasa, J ^{[1
]}

机构：

[1] Univ Barcelona, Fac Quim, Dept Quim Organ, E-08028 Barcelona, Catalonia, Spain

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 03期

关键词：

D O I：

10.1021/ol991359z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A procedure for the conversion of azides to amines, which uses NaBH4 and catalytic amounts of tin(lV) 1,2-benzenedithiolate, is disclosed. Primary, secondary, tertiary, aromatic, and heteroaromatic azides are reduced in excellent yields under very mild conditions.

引用

页码：397 / 399

页数：3

共 43 条

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