Mechanistic questions about the reaction of molecular oxygen with palladium in oxidase catalysis

被引：197

作者：

Gligorich, Keith M. ^{[1
]}

Sigman, Matthew S. ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 40期

关键词：

homogeneous catalysis; molecular oxygen; oxidation; palladium; reaction mechanisms;

D O I：

10.1002/anie.200602138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Which pathway? Aerobic Pd-catalyzed oxidation reactions couple organic-substrate oxidation to the reduction of O2. Two pathways are prevalent for the regeneration of the active PdII catalyst (see scheme; SubH2= substrate; SubOx = oxidized substrate), and recent studies have provided a deeper fundamental understanding of the interactions of Pd with O2. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6612 / 6615

页数：4

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