Transition metal catalyzed Atom Transfer Radical Polymerization (ATRP): from heterogeneous to homogeneous catalysis using 1,1O-phenantroline and its derivatives as new copper(I) ligands

被引：66

作者：

Destarac, M ^{[1
]}

Bessiere, JM ^{[1
]}

Boutevin, B ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,UPRESA 5076,LAB CHIM APPL,F-34296 MONTPELLIER 5,FRANCE

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 11期

关键词：

D O I：

10.1002/marc.1997.030181103

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Atom Transfer Radical Polymerization (ATRP) of styrene is investigated in both heterogeneous and homogeneous media using 1-phenylethyl chloride (1-PECl)/CuCl/1,10-phenantroline and derivatives as initiating systems. Using a 1-PECl/CuCl/4,7-diphenyl-1,10-phenantroline system in 1,2-dimethoxybenzene as a solvent at 130 degrees C, homogeneous ATRP of styrene leads to polymers with polydispersities down to 1,1. These new systems are compared with previously described 4,4'-disubstituted 2,2'-bipyridine-based systems in terms of kinetics and quality of control.

引用

页码：967 / 974

页数：8

共 29 条

[1] Living radical polymerization of methyl methacrylate with ruthenium complex: Formation of polymers with controlled molecular weights and very narrow distributions [J].

Ando, T ;

Kato, M ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1996, 29 (03) :1070-1072

[2]

BENHADDA T, 1988, POLYHEDRON, V7, P575

[3] Controlled radical polymerization - Synthesis of chloromethyl styrene/styrene block copolymers [J].

Bertin, D ;

Boutevin, B .

POLYMER BULLETIN, 1996, 37 (03) :337-344

[4]

BERTIN D, 1996, Patent No. 9605909

[5]

BRANDT WA, 1954, CHEM REV, P959

[6] LIVING RADICAL POLYMERIZATION - KINETIC RESULTS [J].

CATALA, JM ;

BUBEL, F ;

HAMMOUCH, SO .

MACROMOLECULES, 1995, 28 (24) :8441-8443

[7]

Destarac M., 1997, POLYM PREPR, V38, P677

[8] LIVING RADICAL POLYMERIZATION INVOLVING OXYGEN-CENTERED SPECIES ATTACHED TO PROPAGATING CHAIN ENDS [J].

DRULINER, JD .

MACROMOLECULES, 1991, 24 (23) :6079-6082

[9]

GEORGES MK, 1995, MACROMOLECULES, V28, P8453

[10] Controlled radical polymerization of methacrylic monomers in the presence of a bis(ortho-chelated) arylnickel(II) complex and different activated alkyl halides [J].

Granel, C ;

Dubois, P ;

Jerome, R ;

Teyssie, P .

MACROMOLECULES, 1996, 29 (27) :8576-8582

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