119Sn Mossbauer study of nickel-tin anodes for rechargeable lithium-ion batteries

被引：15

作者：

Naille, S. ^{[1
]}

Lippens, P. E. ^{[1
]}

Morato, F. ^{[1
]}

Olivier-Fourcade, J. ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Agregats Mol & Mat Inorgan, CNRS, UMR 5072, F-34095 Montpellier 5, France

来源：

HYPERFINE INTERACTIONS | 2006年 / 167卷 / 1-3期

关键词：

Sn-119 Mossbauer spectrometry; lithium-ion batteries; intermetallic compounds; lithium insertion mechanism;

D O I：

10.1007/s10751-006-9357-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Sn-119 Mossbauer spectrometry has been carried out on Ni-Sn alloys (Ni3Sn LT, Ni3Sn2 LT and Ni3Sn4) and combined with ab initio calculations. Lithium insertion/extraction mechanisms of the most interesting compound (Ni3Sn4) have been studied from Sn-119 Mossbauer measurements. The first discharge shows a plateau close to 0.0 V, which can be attributed to the formation of the Li7Sn2 alloy.

引用

收藏

页码：785 / 790

页数：6

相关论文

共 18 条

[1] THE ELECTRIC-FIELD GRADIENT DIRECTION IN TIN METAL [J].

BAHGAT, AA .

PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1980, 97 (02) :K129-K132

[2] FULL-POTENTIAL, LINEARIZED AUGMENTED PLANE-WAVE PROGRAMS FOR CRYSTALLINE SYSTEMS [J].

BLAHA, P ;

SCHWARZ, K ;

SORANTIN, P ;

TRICKEY, SB .

COMPUTER PHYSICS COMMUNICATIONS, 1990, 59 (02) :399-415

[3] Electroless Cu-plated Ni3Sn4 alloy used as anode material for lithium ion battery [J].

Cheng, XQ ;

Shi, PF .

JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 391 (1-2) :241-244

[4] 119Sn Mossbauer study of LixSn alloys prepared electrochemically [J].

Chouvin, J ;

Olivier-Fourcade, J ;

Jumas, JC ;

Simon, B ;

Godiveau, O .

CHEMICAL PHYSICS LETTERS, 1999, 308 (5-6) :413-420

[5] MECHANISMS FOR LITHIUM INSERTION IN CARBONACEOUS MATERIALS [J].

DAHN, JR ;

ZHENG, T ;

LIU, YH ;

XUE, JS .

SCIENCE, 1995, 270 (5236) :590-593

[6] STRUCTURAL-PROPERTIES OF CO3SN2,NI3SN2 AND SOME TERNARY DERIVATIVES [J].

FJELLVAG, H ;

KJEKSHUS, A .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1986, 40 (01) :23-30

[7] Lithium alloy negative electrodes [J].

Huggins, RA .

JOURNAL OF POWER SOURCES, 1999, 81 :13-19

[8] STRUCTURE REFINEMENT OF NI3SN4 [J].

JEITSCHKO, W ;

JABERG, B .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1982, 38 (FEB) :598-600

[9] Characterization of commercially available lithium-ion batteries [J].

Johnson, BA ;

White, RE .

JOURNAL OF POWER SOURCES, 1998, 70 (01) :48-54

[10] LixCu6Sn5 (0<x<13):: An intermetallic insertion electrode for rechargeable lithium batteries [J].

Kepler, KD ;

Vaughey, JT ;

Thackeray, MM .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (07) :307-309