Chemical degradation of EDTA and DTPA in a totally chlorine free (TCF) effluent

被引:26
作者
Rodríguez, JB [1 ]
Mutis, A [1 ]
Yeber, MC [1 ]
Freer, J [1 ]
Baeza, J [1 ]
Mansilla, HD [1 ]
机构
[1] Univ Concepcion, Lab Renewable Resources, Concepcion, Chile
关键词
AOPs; chelants; DTPA; EDTA; ozone; TCF effluent; UV;
D O I
10.2166/wst.1999.0721
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this work, a Synthetic TCF effluent containing vanillin, glyoxal, sodium formate, sodium acetate and the chelanting agents EDTA and DTPA was treated using, O(3), O(3)/H(2)O(2), O(3)/UV, UV, UV/H(2)I(2) and UV/H(2)O(2)/O(3) at pH 7 and 11. The best results were obtained in the O(3)/UV process. Ozone alone did not degrade EDTA neither DTPA. A combined O(3)/UV (pH 7.0 by 15 min)-biological treatment was very efficient in the removal of the chelants (98%) and COD (95%). (C) 1999 Published by Elsevier Science Ltd on behalf of the IAWQ. All rights reserved.
引用
收藏
页码:267 / 272
页数:6
相关论文
共 10 条
[1]  
*APHA AWWA WPCF, 1992, STAND METH EX WAT WA
[2]  
LARISCH B, 1996, WAT SCI TECH, V35, P163
[3]  
MATTHEW LH, 1996, WAT SCI TECH, V35, P25
[4]  
Mutis A, 1998, 7TH INTERNATIONAL CONFERENCE ON BIOTECHNOLOGY IN THE PULP AND PAPER INDUSTRY - POSTER PRESENTATIONS VOL C, pC235
[5]  
MUTIS A, 1998, 2 INT C ADV WAST TRE
[6]   Determination of dissolved and adsorbed EDTA species in water and sediments by HPLC [J].
Nowack, B ;
Kari, FG ;
Hilger, SU ;
Sigg, L .
ANALYTICAL CHEMISTRY, 1996, 68 (03) :561-566
[7]   DETERMINATION OF EDTA AND DTPA AS THEIR FE(III) COMPLEXES IN PULP AND PAPER-MILL PROCESS AND WASTE-WATERS BY LIQUID-CHROMATOGRAPHY [J].
SILLANPAA, M ;
RAIMO, KB ;
SIHVONEN, ML .
ANALYTICA CHIMICA ACTA, 1995, 303 (2-3) :187-192
[8]  
Thomas RAP, 1998, APPL ENVIRON MICROB, V64, P1319
[9]  
van Ginkel CG, 1999, TAPPI J, V82, P138
[10]  
VIRTAPOHJA J, 1996, TAPPI 1996 P INT PUL, P537