Chemically selective sensing through layer-by-layer incorporation of biorecognition into thin film substrates for surface-enhanced resonance Raman scattering

被引：43

作者：

Pieczonka, Nicholas P. W. ^{[1
]}

Goulet, Paul J. G. ^{[1
]}

Aroca, Ricardo F. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Mat & Surface Sci Grp, Windsor, ON N9B 3P4, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 39期

关键词：

NANOPARTICLES; SILVER; SPECTROSCOPY; PROTEINS; AVIDIN;

D O I：

10.1021/ja0644327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, the fabrication, characterization, and application of avidin/Ag nanoparticle layer-by-layer (LbL) films as chemically selective substrates for surface-enhanced resonance Raman scattering (SERRS) is demonstrated. The biospecific interaction between avidin and the small molecule biotin, one of the strongest known to exist in nature, is exploited to preferentially capture biotinylated species from solution. This highly favored adsorption is shown to yield SERRS concentration enhancements and improved detection sensitivities of ca. 102 for commercially available and in situ prepared biotinylated species over their nontagged counterparts. Copyright © 2006 American Chemical Society.

引用

页码：12626 / 12627

页数：2

共 17 条

[1] Role of nanoparticle surface charge in surface-enhanced Raman scattering [J].

Alvarez-Puebla, RA ;

Arceo, E ;

Goulet, PJG ;

Garrido, JJ ;

Aroca, RF .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (09) :3787-3792

[2] Layer-by-layer construction of multilayer thin films composed of avidin and biotin-labeled poly(amine)s [J].

Anzai, J ;

Kobayashi, Y ;

Nakamura, N ;

Nishimura, M ;

Hoshi, T .

LANGMUIR, 1999, 15 (01) :221-226

[3] Nanoparticles with Raman spectroscopic fingerprints for DNA and RNA detection [J].

Cao, YWC ;

Jin, RC ;

Mirkin, CA .

SCIENCE, 2002, 297 (5586) :1536-1540

[4] Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].

Decher, G .

SCIENCE, 1997, 277 (5330) :1232-1237

[5] A layer-by-layer film of chitosan in a taste sensor application [J].

dos Santos, DS ;

Riul, A ;

Malmegrim, RR ;

Fonseca, FJ ;

Oliveira, ON ;

Mattoso, LHC .

MACROMOLECULAR BIOSCIENCE, 2003, 3 (10) :591-595

[6] Some interesting properties of metals confined in time and nanometer space of different shapes [J].

El-Sayed, MA .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :257-264

[7] Use of colloidal gold surface plasmon resonance peak shift to infer affinity constants from the interactions between protein antigens and antibodies specific for single or multiple epitopes [J].

Englebienne, P .

ANALYST, 1998, 123 (07) :1599-1603

[8] Surface-enhanced Raman scattering on dendrimer/metallic nanoparticle layer-by-layer film substrates [J].

Goulet, PJG ;

dos Santos, DS ;

Alvarez-Puebla, RA ;

Oliveira, ON ;

Aroca, RF .

LANGMUIR, 2005, 21 (12) :5576-5581

[9]

GOULET PJG, IN PRESS NEW APPROAC

[10] A nanoscale optical blosensor: Sensitivity and selectivity of an approach based on the localized surface plasmon resonance spectroscopy of triangular silver nanoparticles [J].

Haes, AJ ;

Van Duyne, RP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (35) :10596-10604

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