Asymmetric catalysis with CO2:: Direct synthesis of optically active propylene carbonate from racemic epoxides

被引：332

作者：

Lu, XB ^{[1
]}

Liang, B

Zhang, YJ

Tian, YZ

Wang, YM

Bai, CX

Wang, H

Zhang, R

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 12期

关键词：

D O I：

10.1021/ja049734s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication describes a convenient route to optically active propylene carbonate by a catalytic kinetic resolution process resulting from the coupling reaction of CO2 and racemic epoxides using simple chiral SalenCo(III)/quaternary ammonium halide catalyst systems. Copyright © 2004 American Chemical Society.

引用

页码：3732 / 3733

页数：2

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