Stereoselective transformations leading to pentono-1,4-lactones

被引：7

作者：

Rao, BV

Lahiri, S

机构：

[1] Organic III, Indian Inst. of Chemical Technology

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1996年 / 15卷 / 08期

关键词：

D O I：

10.1080/07328309608005703

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The readily available 2,3-O-isopropylidene-D-erythrose has been stereoselectively transformed into L-ribono and D/L lyxonolactone derivatives via dihydroxylation, iodolactonisation and epoxidation. Also D-ribono-1,4-lactone was converted into L-lyxono-1,4-lactone. These lactones are considered as important starting materials for the synthesis of several chiral compounds. Our observations during these transformations are also presented.

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页码：975 / 984

页数：10

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