Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers

被引：491

作者：

Luzinov, I ^{[1
]}

Minko, S

Tsukruk, VV

机构：

[1] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29634 USA

[2] Clarkson Univ, Dept Chem, Potsdam, NY 13699 USA

[3] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA

来源：

PROGRESS IN POLYMER SCIENCE | 2004年 / 29卷 / 07期

基金：

美国国家科学基金会;

关键词：

adaptive materials; responsive materials; smart materials; intelligent materials; switchable materials; polymer surface; polymer interface; polymer brush;

D O I：

10.1016/j.progpolymsci.2004.03.001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The present manuscript offers an overview of the current state of affairs within the research field of adaptive and environmentally sensitive polymer surfaces designed to respond to external stimuli in a controlled and predictable manner. Intensive study in the field of the adaptive/responsive surfaces began several decades ago in an attempt to understand relationships between bulk properties/composition of pristine polymeric materials and their surface characteristics. With time, the focus of the research has moved to the design of materials with 'smart' or 'intelligent' surface behavior. This review describes a number of approaches that has been employed to fabricate such materials, which include but not limited to (a) synthesis of functional polymers with specific composition and architecture; (b) blending of a virgin polymer material with small amounts of (macro)molecular additive; (c) surface modification by various chemical/physical treatment. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：635 / 698

页数：64

共 222 条

[1] Polymer brushes by living anionic surface initiated polymerization on flat silicon (SiOx) and gold surfaces:: Homopolymers and block copolymers [J].

Advincula, R ;

Zhou, QG ;

Park, M ;

Wang, SG ;

Mays, J ;

Sakellariou, G ;

Pispas, S ;

Hadjichristidis, N .

LANGMUIR, 2002, 18 (22) :8672-8684

[2] Biomimetic pathways for assembling inorganic thin films [J].

Aksay, IA ;

Trau, M ;

Manne, S ;

Honma, I ;

Yao, N ;

Zhou, L ;

Fenter, P ;

Eisenberger, PM ;

Gruner, SM .

SCIENCE, 1996, 273 (5277) :892-898

[3] ADSORPTION OF CHAIN MOLECULES WITH A POLAR HEAD A-SCALING DESCRIPTION [J].

ALEXANDER, S .

JOURNAL DE PHYSIQUE, 1977, 38 (08) :983-987

[4]

[Anonymous], POLYM PREPRINTS DIV

[5] CHARACTERIZATION OF THE BRUSH REGIME FOR GRAFTED POLYMER LAYERS AT THE SOLID-LIQUID INTERFACE [J].

AUROY, P ;

AUVRAY, L ;

LEGER, L .

PHYSICAL REVIEW LETTERS, 1991, 66 (06) :719-722

[6] Designing soft reactive adhesives by controlling polymer chemistry [J].

Aymonier, A ;

Papon, E .

MRS BULLETIN, 2003, 28 (06) :424-427

[7] BLOCK COPOLYMER THERMODYNAMICS - THEORY AND EXPERIMENT [J].

BATES, FS ;

FREDRICKSON, GH .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1990, 41 (01) :525-557

[8] Synthesis of polymer brushes on silicate substrates via reversible addition fragmentation chain transfer technique [J].

Baum, M ;

Brittain, WJ .

MACROMOLECULES, 2002, 35 (03) :610-615

[9] Suitability of hyperbranched polyester for sensoric applications - investigation with reflectometric interferance spectroscopy [J].

Belge, G ;

Beyerlein, D ;

Betsch, C ;

Eichhorn, KJ ;

Gauglitz, G ;

Grundke, K ;

Voit, B .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2002, 374 (03) :403-411

[10] Temperature-responsive surface-functionalized polyethylene films [J].

Bergbreiter, DE ;

Ponder, BC ;

Aguilar, G ;

Srinivas, B .

CHEMISTRY OF MATERIALS, 1997, 9 (02) :472-477

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