Phase transition temperatures and piezoelectric properties of (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-BaTiO3 lead-free piezoelectric ceramics

被引：188

作者：

Hiruma, Yuji ^{[1
]}

Nagata, Hajime ^{[1
]}

Takenaka, Tadashi ^{[1
]}

机构：

[1] Tokyo Univ Sci, Fac Sci & Technol, Dept Elect Engn, Noda, Chiba 2788510, Japan

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS | 2006年 / 45卷 / 9B期

关键词：

lead-free piezoelectric ceramics; dielectric properties; piezoelectric properties; phase transition; (Bi1/2Na1/2)TiO3; (Bi1/2K1/2)TiO3;

D O I：

10.1143/JJAP.45.7409

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The phase transition temperatures of x(Bi1/2Na1/2)TiO3-y(Bi1/2K1/2)TiO3-zBaTiO(3)) [x + y + z = 1, y : z = 2 : 1] [abbreviate to BNBK2:1(x)] ceramics were investigated using electrical measurements. We discussed the determination of the depolarization temperature, T-d, and defined the T-d for (Bi1/2Na1/2)TiO3 (BNT)-based solid solutions. We also determined the rhombohedral-tetragonal phase transition temperatures, TR-T, for BNBK2:1(x), and verified them using dielectric and piezoelectric measurements. It was demonstrated that TR-T corresponded with T-d at x = 0.94. The existence of an intermediate phase with ferroelectric and antiferroelectric properties at temperatures higher than the T-d around the morphotropic phase boundary (MPB) was also revealed.

引用

页码：7409 / 7412

页数：4

共 16 条

[1] PIEZOELECTRIC PROPERTIES OF POLYCRYSTALLINE LEAD TITANATE ZIRCONATE COMPOSITIONS [J].

BERLINCOURT, DA ;

CMOLIK, C ;

JAFFE, H .

PROCEEDINGS OF THE INSTITUTE OF RADIO ENGINEERS, 1960, 48 (02) :220-229

[2] Processing and electromechanical properties of (Bi0.5Na0.5)((1-1.5x))LaxTiO3 ceramics [J].

Herabut, A ;

Safari, A .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1997, 80 (11) :2954-2958

[3]

Hiruma Y., 2006, CERAM T, V174, P139

[4] Investigation of the structure and phase transitions in the novel A-site substituted distorted perovskite compound Na0.5Bi0.5TiO3 [J].

Jones, GO ;

Thomas, PA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 :168-178

[5]

Kainik, 1960, SOV PHYS SOLID STATE, V2, P2982

[6] (Bi1/2Na1/2)TiO3-(Bi1/2K1/2)TiO3-BaTiP3-Based lead-free piezoelectric ceramics [J].

Makiuchi, Y ;

Aoyagi, R ;

Hiruma, Y ;

Nagata, H ;

Takenaka, T .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (6B) :4350-4353

[7]

Nagata H, 2005, CERAM TRANS, V167, P213

[8] Large piezoelectric constant and high Curie temperature of lead-free piezoelectric ceramic ternary system based on bismuth sodium titanate-bismuth potassium titanate-barium titanate near the morphotropic phase boundary [J].

Nagata, H ;

Yoshida, M ;

Makiuchi, Y ;

Takenaka, T .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2003, 42 (12) :7401-7403

[9] Phase relations in the system of (Na1/2Bi1/2)TiO3-PbTiO3 .1. Structure [J].

Park, SE ;

Hong, KS .

JOURNAL OF APPLIED PHYSICS, 1996, 79 (01) :383-387

[10] PECULIARITIES OF PHASE-TRANSITIONS IN SODIUM-BISMUTH TITANATE [J].

PRONIN, IP ;

SYRNIKOV, PP ;

ISUPOV, VA ;

EGOROV, VM ;

ZAITSEVA, NV .

FERROELECTRICS, 1980, 25 (1-4) :395-397

← 1 2 →