Transverse dephasing optimised NMR spectroscopy in solids:: Natural-abundance 13C correlation spectra

被引：36

作者：

De Paëpe, G

Lesage, A

Steuernagel, S

Emsley, L

机构：

[1] Ecole Normale Super Lyon, Chim Lab, CNRS, UMR 5182,CEA 23V, F-69364 Lyon, France

[2] Bruker BioSpin GMBH, D-76287 Rheinstetten, Germany

来源：

CHEMPHYSCHEM | 2004年 / 5卷 / 06期

关键词：

correlation spectroscopy; INADEQUATE; madic-angle spinning; scalar coupling; solids;

D O I：

10.1002/cphc.200301062

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Natural-abundance correlation experiments: By a careful optimisation of the heteronuclear decoupling sequences applied during the double quantum excitation and reconversion intervals, magic-angle-spinning solid-state 13C-refocused INADEQUATE experiments are demonstrated to be practicable on several medium-sized molecules at natural abundance in reasonable experimental times (see picture).

引用

收藏

页码：869 / 875

页数：7

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