Oxidation State-Specific Fluorescent Method for Palladium(II) and Platinum(IV) Based on the Catalyzed Aromatic Claisen Rearrangement

被引：96

作者：

Garner, Amanda L. ^{[1
]}

Koide, Kazunori ^{[1
]}

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 49期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ja8065539

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Contamination of active pharmaceutical ingredients and healthcare products with oxidized forms of palladium and platinum are important problems. We report a convenient fluorogenic probe based on the catalyzed aromatic Claisen rearrangement capable of detecting Pd-II and Pt-IV. Using this probe, we can fluorescentty detect Pd-III in functionalized organic compounds and Pt-IV in Pt-0-water without sample pretreatment. This method may find broad applications in the pharmaceutical industry, the environment, and Pd/Pt quality control.

引用

页码：16472 / +

页数：3

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