Electrochemical switching of the cubic nonlinear optical properties of an aryldiethynyl-linked heterobimetallic complex between three distinct states

被引：161

作者：

Samoc, Marek ^{[1
]}

Gauthier, Nicolas

Cifuentes, Marie P.

Paul, Frederic

Lapinte, Claude

Humphrey, Mark G.

机构：

[1] Australian Natl Univ, Res Sch Phys Sci & Engn, Laser Phys Ctr, Canberra, ACT 0200, Australia

[2] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

[3] Australian Natl Univ, Dept Chem, Canberra, ACT 0200, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 44期

关键词：

alkynyl ligands; electrochemistry; molecular switches; nonlinear optics;

D O I：

10.1002/anie.200602684

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Successive oxidation processes in a heterobimetallic iron-ruthenium complex (see picture) "switch" the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7376 / 7379

页数：4

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