Mixed-valence states in MMX-chains complex, Pt-2(dta)(4)I

被引：27

作者：

Kitagawa, H

Onodera, N

Ahn, JS

Mitani, T

Kim, M

Ozawa, Y

Toriumi, K

Yasui, K

Manabe, T

Yamashita, M

机构：

[1] HIMEJI INST TECHNOL,HIMEJI,HYOGO 67122,JAPAN

[2] NAGOYA UNIV,CHIKUSA KU,NAGOYA,AICHI 46401,JAPAN

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 285卷

关键词：

D O I：

10.1080/10587259608030818

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Physical and structural properties of the MMX-type halogen-bridged mixed-valence complex, Pt-2(dta)(4)I (dta = CH3CS2) were investigated. This complex exhibits metallic conduction above room temperature, which is the first observation in halogen-bridged 1-D transition-metal complexes. Below 300 K, the metal-semiconductor transition was observed. The mixed-valence state of this compound is discussed.

引用

页码：311 / 316

页数：6

共 14 条

[1] HALOGEN OXIDATION OF TETRAKIS(DITHIOACETATO)DIPLATINUM(II) COMPLEXES, PT2(CH3CS2)4 - SYNTHESIS AND CHARACTERIZATION OF PT2(CH3CS2)4X2 (X = CL, BR, I) AND STRUCTURAL, ELECTRICAL, AND OPTICAL-PROPERTIES OF LINEAR-CHAIN (MU-IODO)TETRAKIS(DITHIOACETATO)DIPLATINUM, PT2(CH3CS2)4I [J].