Coordination chemistry of diselenophosphinate complexes:: The X-ray single-crystal structures of [K(Se2PPh2)(THF)2]2 and [In(Se2PPh2)3]•L (L = THF, PhMe)

被引：52

作者：

Davies, RP ^{[1
]}

Francis, CV ^{[1
]}

Jurd, APS ^{[1
]}

Martinelli, MG ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 16期

关键词：

D O I：

10.1021/ic049567x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of potassium diphenylphosphide with elemental selenium is shown to give [K(Se2PPh2)(THF)(2)](2) 1, which further reacts with InCl3 to yield [In(Se2PPh2)(3)] 2. Crystallization of 2 from either THF or PhMe gave 2.THF or 2.PhMe, respectively, both of which form loosely linked dimers in the solid state via Se...Se intermolecular van der Waals interactions. Decomposition of 2 has been studied by TGA.

引用

页码：4802 / 4804

页数：3

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