Synthesis of cyclopropylsilanols by the Simmons-Smith reaction of alkenylsilanols and lithium alkenylsilanolates

被引：45

作者：

Hirabayashi, K ^{[1
]}

Mori, A ^{[1
]}

Hiyama, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,YOKOHAMA,KANAGAWA 226,JAPAN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(96)02326-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkenylsilanols and the corresponding lithium silanolates prepared in situ by the reaction of cyclic siloxanes with alkenyllithiums are transformed to the corresponding cyclopropylsilanols under the Simmons-Smith reaction conditions. The obtained cyclopropylsilanols are further converted into the corresponding cyclopropanols by the Tamao oxidation. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：461 / 464

页数：4

共 18 条

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