Carbon-carbon bond activation by electrophilic complexes of cobalt: Anomalous [3+2+2] allyl/alkyne cycloaddition reactions and [5+2] cyclopentenyl/alkyne insertion-ring expansion reactions

被引：53

作者：

Dzwiniel, TL ^{[1
]}

Etkin, N ^{[1
]}

Stryker, JM ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1999年 / 121卷 / 45期

关键词：

D O I：

10.1021/ja992598k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：10640 / 10641

页数：2

共 26 条

[1] CARBON HYDROGEN AND CARBON CARBON BOND ACTIVATION WITH HIGHLY ELECTROPHILIC TRANSITION-METAL COMPLEXES [J].

BERCAW, JE .

PURE AND APPLIED CHEMISTRY, 1990, 62 (06) :1151-1154

[2] ETHYLENE INSERTION AND BETA-HYDROGEN ELIMINATION FOR PERMETHYLSCANDOCENE ALKYL COMPLEXES - A STUDY OF THE CHAIN PROPAGATION AND TERMINATION STEPS IN ZIEGLER-NATTA POLYMERIZATION OF ETHYLENE [J].

BURGER, BJ ;

THOMPSON, ME ;

COTTER, WD ;

BERCAW, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) :1566-1577

[3] Platinum-mediated coupling of alkynols and alpha-diazoesters. Pseudocatalytic synthesis of tetrahydrofuranylidene esters via alkyl migration to a coordinated carbene [J].

Casty, GL ;

Stryker, JM .

ORGANOMETALLICS, 1997, 16 (14) :3083-3085

[4] THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1985, 85 (04) :245-269

[5] Facile carbon-carbon bond cleavage in an (eta(3)-cyclooctenyl)cobalt complex exhibiting agostic C...H...Co bonding [J].

Cracknell, RB ;

Nicholls, JC ;

Spencer, JL .

ORGANOMETALLICS, 1996, 15 (01) :446-448

[6] KINETIC AND MECHANISTIC ASPECTS OF PROPENE OLIGOMERIZATION WITH IONIC ORGANOZIRCONIUM AND ORGANOZIRHAFNIUM COMPOUNDS - CRYSTAL-STRUCTURES OF [CP-STAR-2MME(THT)]+[BPH4]-(M = ZR, HF) [J].

ESHUIS, JJW ;

TAN, YY ;

MEETSMA, A ;

TEUBEN, JH ;

RENKEMA, J ;

EVENS, GG .

ORGANOMETALLICS, 1992, 11 (01) :362-369

[7] Reversible migratory insertion beta-alkyl elimination in alpha-agostic alkylniobium alkyne complexes [J].

Etienne, M ;

Mathieu, R ;

Donnadieu, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (14) :3218-3228

[8] Cobalt-mediated intermolecular allyl/alkyne [3+2+2] cycloaddition reactions. A practical metal template for convergent synthesis of functionalized seven-membered rings [J].

Etkin, N ;

Dzwiniel, TL ;

Schweibert, KE ;

Stryker, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (37) :9702-9703

[9] CATIONIC ZIRCONIUM AND HAFNIUM ISOBUTYL COMPLEXES AS MODELS FOR INTERMEDIATES IN METALLOCENE-CATALYZED PROPYLENE POLYMERIZATIONS - DETECTION OF AN ALPHA-AGOSTIC INTERACTION IN (C5ME5)2HF(CH2CHME2)(PME3)+ [J].

GUO, ZY ;

SWENSON, DC ;

JORDAN, RF .

ORGANOMETALLICS, 1994, 13 (04) :1424-1432

[10] COMPETITIVE CHAIN TRANSFER BY BETA-HYDROGEN AND BETA-METHYL ELIMINATION FOR THE MODEL ZIEGLER-NATTA OLEFIN POLYMERIZATION SYSTEM [ME2SI(ETA(5)-C5ME4)2]SC(CH2CH(CH3)2)(PME3) [J].

HAJELA, S ;

BERCAW, JE .

ORGANOMETALLICS, 1994, 13 (04) :1147-1154

← 1 2 3 →