Ring-opening polymerization of α-chloro-∈-caprolactone and chemical modification of poly(α-chloro-∈-caprolactone) by atom transfer radical processes

被引：130

作者：

Lenoir, S ^{[1
]}

Riva, R ^{[1
]}

Lou, X ^{[1
]}

Detrembleur, C ^{[1
]}

Jérôme, R ^{[1
]}

Lecomte, P ^{[1
]}

机构：

[1] Univ Liege, CERM, B-4000 Liege, Belgium

来源：

MACROMOLECULES | 2004年 / 37卷 / 11期

关键词：

D O I：

10.1021/ma035003l

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A highly versatile strategy was implemented in order to attach a range of polymer grafts and functional groups along the backbone of poly(c-caprolactone). alpha-Chloro-epsilon-caprolactone (alphaClepsilonCL) was first prepared by the Baeyer-Villiger oxidation of alpha-chlorocyclohexanone. This monomer (alphaClepsilonCL) was then copolymerized with epsilon-caprolactone in the presence of 2,2-dibutyl-2-stanna-1,3-dioxepane. Finally, the pendant activated chlorides of the copolymer were used to initiate (i) the "grafting from" of poly(methyl methacrylate) by atom transfer radical polymerization and (ii) the grafting of benzoate groups by atom transfer radical addition of 3-butenyl benzoate.

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页码：4055 / 4061

页数：7

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