Application of hole theory to the viscosity of ionic and molecular liquids

被引：243

作者：

Abbott, AP ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

CHEMPHYSCHEM | 2004年 / 5卷 / 08期

关键词：

hole theory; ionic liquids; liquids; salts; viscosity;

D O I：

10.1002/cphc.200400190

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Holey waters: The viscosity of a range of ionic and molecular fluids is shown to be proportional to the probability of finding an adjacent hole of sufficient dimensions to permit movement. An expression for the viscosity of an ideal gas can be modified by this probability function to account for the viscosity of liquids (see graphic).

引用

页码：1242 / 1246

页数：5

共 19 条

[1] ABBOTT AP, UNPUB
[2] BOCKRIS JOM, 1970, MODERN ELECTROCHEMIS, V1, pCH6
[3] Branco LC, 2002, CHEM-EUR J, V8, P3671, DOI 10.1002/1521-3765(20020816)8:16<3671::AID-CHEM3671>3.0.CO
[4] 2-9
[5] Cavities in ionic liquids
Bresme, F
Alejandre, J
[J]. JOURNAL OF CHEMICAL PHYSICS, 2003, 118 (09) : 4134 - 4139
[6] Dzyuba SV, 2002, CHEMPHYSCHEM, V3, P161, DOI 10.1002/1439-7641(20020215)3:2<161::AID-CPHC161>3.0.CO
[7] 2-3
[8] Frenkel Ya.I., 1975, Kinetic theory of liquid
[9] Furth R, 1941, P CAMB PHILOS SOC, V37, P252
[10] Fürth R, 1941, P CAMB PHILOS SOC, V37, P281

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