A series of inorganic-organic hybrid composite solids based on molybdenum oxide chains

被引：82

作者：

Chen, Li-Juan ^{[1
]}

He, Xiang ^{[1
]}

Xia, Chang-Kun ^{[1
]}

Zhang, Quan-Zheng ^{[1
]}

Chen, Jiu-Tong ^{[1
]}

Yang, Wen-Bin ^{[1
]}

Lu, Can-Zhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 09期

关键词：

D O I：

10.1021/cg060228j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Six inorganic-organic compounds based on [MoxOy](n-) chains, [Ag-2(quinoxaline)(2)Mo4O13] (1), [Cu-2(DMPz)(2)Mo4O13] (2) (DMPz = 2,5-dimethylpyrazine), [Cu-2(4-PBIM)(2)Mo4O13] (3) [4-PBIM = 2-(4-pyridyl) benzimidazole], [Cu(OPBIM)(H2O) Mo3O10]center dot H2O (4) [OPBIM = 2-(2-ol-3-pyridinio) benzimidazole], [Co(3-HPBIM)(2) (H2O)(2)Mo6O20] (5) [3-HPBIM = 2-(3-pyridyl)-benzimidazolium], [Ni(3-HPBIM)(2)(H2O)(2)Mo6O20] (6), have been hydrothermally synthesized and characterized by single-crystal X- ray diffraction. Compounds 1 and 2 represent the first two examples of three-dimensional frameworks constructed from [Mo8O26](n)(4n-) anion chains integrated by M-L polymeric cation chains. Compounds 3 and 4 reveal the peripheral decorated [Mo8O26](n)(4n-) and [Mo3O10](n)(2n-) one-dimensional chains, respectively. The isostructural compounds 5 and 6 feature two-dimensional networks formed from [Mo3O10](2n)(4n-) infinite chains linked by [Co(3-HPBIM)(2)](4+) fragments. The molybdate chains in compounds 1-3 and 4-6 represent three isomeric forms of [Mo8O26](n)(4n-) and two [Mo3O10](n)(2n-) chains, respectively.

引用

页码：2076 / 2085

页数：10

共 56 条

[1] Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers [J].