Pentasupertetrahedral clusters as building blocks for a three-dimensional sulfide superlattice

被引：66

作者：

Zheng, NF

Bu, XH

Feng, PY ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 36期

关键词：

cluster compounds; hydrothermal synthesis; indium; microporous materials; sulfur;

D O I：

10.1002/anie.200460386

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly mobile extra-framework cations encapsulated in the 3D open-framework architecture of ICF-26 result in remarkably high ion conductivity. The framework is composed of Li4In22S44 18- clusters, which represent the second member of a series of pentasupertetrahedral clusters Pn. The P2 cluster reported here is the largest member of the Pn series so far. In the crystal, each P2 cluster shares all four corners with adjacent P2 clusters (see picture).

引用

页码：4753 / 4755

页数：3

共 31 条

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