Very broad white-emission spectrum based organic light-emitting diodes by four exciplex emission bands

被引:24
作者
Zhu, Jianzhuo [1 ,2 ]
Li, Wenlian [1 ]
Han, Liangliang [1 ,2 ]
Chu, Bei [1 ]
Zhang, Guang [1 ,2 ]
Yang, Dongfang [1 ,2 ]
Chen, Yiren [1 ]
Su, Zisheng [1 ,2 ]
Wang, Junbo [1 ,2 ]
Wu, Shuanghong [1 ,2 ]
Tsuboi, Taiju [3 ]
机构
[1] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
[3] Kyoto Sangyo Univ, Fac Engn, Kita Ku, Kyoto 6038555, Japan
基金
中国国家自然科学基金;
关键词
ELECTROLUMINESCENT DEVICES; INTERFACE; MOLECULES; BLENDS; LAYER;
D O I
10.1364/OL.34.002946
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
White light is emitted by an organic light-emitting diode by inserting two blend layers of m-MTDATA: Al(DBM)(3) and TPD: Bphen between an m-MTDATA hole-transporting layer and a Bphen electron-transporting layer, where m-MTDATA, TPD, Al(DBM)(3), and Bphen are 4,4',4 ''-tris[methylpheny(phenyl)amino]-triphenylamine, N,N'-bis(3-methylphenyl)-N,N'-diphenylbenzidine, tris(dibenzoyl methane)-aluminum, and 4,7-diphenyl-1,10-phenanthroline molecules, respectively. The white-light spectrum consists of four broad bands that arise from blue-emitting TPD/Bphen, green-emitting m-MTDATA/Bphen, orange-emitting TPD/Al(DBM)(3), and red-emitting m-MTDATA/Al(DBM)(3) exciplexes, respectively, and strongly overlap at 400-760 nm. Any monomer emission is not generated. A high-color rendering index of 94.1, Commission Internationale de l'Eclairage-1931(x,y) coordinates of (0.33, 0.35), and correlated color temperature of 5477 K were obtained at 10 V. Discussion is given for the formation mechanism of the four exciplexes. (C) 2009 Optical Society of America
引用
收藏
页码:2946 / 2948
页数:3
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