Molecular nanomagnets: the first 10 years

被引:76
作者
Gatteschi, D
Sessoli, R
机构
[1] Univ Florence, INSTM, I-50019 Sesto Fiorentino, FI, Italy
[2] Univ Florence, Dipartimento Chim, I-50019 Sesto Fiorentino, FI, Italy
关键词
molecular nanomagnets; quantum effects; magnetisation tunnelling; Berry phase in magnets; Glauber dynamics; one-dimensional magnetism;
D O I
10.1016/j.jmmm.2003.12.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We review here the main achievements reached in the field of magnetic molecules in the first 10 years of activity. After introducing the concept of magnetic molecules we report at some length on the archetypal Mn12Ac, pointing out what is understood and what is still left to do. Other systems will also be reported including Fe8 and Mn4. A section will be devoted to magnetic chains and a final section will give perspectives for future developments. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1030 / 1036
页数:7
相关论文
共 30 条
[1]   Spontaneous magnetization in a sulfur-nitrogen radical at 36 K [J].
Banister, AJ ;
Bricklebank, N ;
Lavender, I ;
Rawson, JM ;
Gregory, CI ;
Tanner, BK ;
Clegg, W ;
Elsegood, MRJ ;
Palacio, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (21) :2533-2535
[2]   Glauber slow dynamics of the magnetization in a molecular Ising chain [J].
Caneschi, A ;
Gatteschi, D ;
Lalioti, N ;
Sangregorio, C ;
Sessoli, R ;
Venturi, G ;
Vindigni, A ;
Rettori, A ;
Pini, MG ;
Novak, MA .
EUROPHYSICS LETTERS, 2002, 58 (05) :771-777
[3]   A FERROMAGNETIC TRANSITION AT 1.48-K IN AN ORGANIC NITROXIDE [J].
CHIARELLI, R ;
NOVAK, MA ;
RASSAT, A ;
THOLENCE, JL .
NATURE, 1993, 363 (6425) :147-149
[4]   Single-molecule magnets [J].
Christou, George ;
Gatteschi, Dante ;
Hendrickson, David N. ;
Sessoli, Roberta .
MRS Bulletin, 2000, 25 (11) :66-71
[5]  
Clemente-León M, 1998, ANGEW CHEM INT EDIT, V37, P2842, DOI 10.1002/(SICI)1521-3773(19981102)37:20<2842::AID-ANIE2842>3.0.CO
[6]  
2-B
[7]   Evidence for single-chain magnet behavior in a MnIII-NiII chain designed with high spin magnetic units:: A route to high temperature metastable magnets [J].
Clérac, R ;
Miyasaka, H ;
Yamashita, M ;
Coulon, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (43) :12837-12844
[8]   Direct observation of single-molecule magnets organized on gold surfaces [J].
Cornia, A ;
Fabretti, AC ;
Pacchioni, M ;
Zobbi, L ;
Bonacchi, D ;
Caneschi, A ;
Gatteschi, D ;
Biagi, R ;
Del Pennino, U ;
De Renzi, V ;
Gurevich, L ;
Van der Zant, HSJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (14) :1645-1648
[9]   Origin of second-order transverse magnetic anisotropy in Mn12-acetate -: art. no. 257201 [J].
Cornia, A ;
Sessoli, R ;
Sorace, L ;
Gatteschi, D ;
Barra, AL ;
Daiguebonne, C .
PHYSICAL REVIEW LETTERS, 2002, 89 (25)
[10]   Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound [J].
Coronado, E ;
Galán-Mascarós, JR ;
Gómez-García, CJ ;
Laukhin, V .
NATURE, 2000, 408 (6811) :447-449