Nitrogen complexes formation during NO-C reaction at low temperature in presence of O2 and H2O

被引：35

作者：

García, P

Coloma, F

de Lecea, CSM

Mondragón, F

机构：

[1] Univ Alicante, Fac Sci, Dept Inorgan Chem, Alicante 03080, Spain

[2] Univ Antioquia, Inst Chem, Medellin, Colombia

来源：

FUEL PROCESSING TECHNOLOGY | 2002年 / 77卷

关键词：

NO-carbon reaction; nitrogen complexes; oxygen complexes;

D O I：

10.1016/S0378-3820(02)00014-0

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Oxygen and nitrogen complexes formation in coal char due to its reaction with NO at 100 degreesC in presence or absence of O-2 and/or H2O was studied by XPS. Fort-nation of -NO2 and pyridinic complexes and a considerable increment of oxygen complex was observed. The -NO2 complexes can be formed in all cases, even when there is no molecular oxygen present in the gas mixture. The presence of O-2 and/or H2O promotes their fort-nation. Apparently, this complex can be formed by the presence of C(O) complexes next to the site capable of chemisorbing NO. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：255 / 259

页数：5

共 8 条

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