Preparation and structure of [RhCl(nbd)(dmap)] (nbd = bicyclo[2.2.1]hepta-2,5-diene; dmap = 4-(N,N-dimethylamino)pyridine)

被引：11

作者：

Takenaka, Y ^{[1
]}

Osakada, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2000年 / 73卷 / 01期

关键词：

D O I：

10.1246/bcsj.73.129

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

4-(N,N-Dimethylamino)pyridine (dmap) reacts with [{RhCl(nbd)}(2)] to give [RhCl(nbd)(dmap)] (1), which was characterized by X-ray crystallography and NMR spectroscopy. The crystal structure and dynamic behavior of the molecule in solution are compared with those of [RhCl(nbd)(PPh3)] (2).

引用

页码：129 / 130

页数：2

共 23 条

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