Reaction of indium bromide with 1,4-dilithiotetraphenylbutadiene.: Synthesis and molecular structure of (Et2O)2Li(Br)2In{(C4Ph4)}2In(Br)2Li(OEt2)2:: A novel ten-membered-ring organometallic complex

被引：12

作者：

Beck, BC ^{[1
]}

Su, JR ^{[1
]}

Wei, PP ^{[1
]}

Li, XW ^{[1
]}

Robinson, GH ^{[1
]}

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 07期

关键词：

D O I：

10.1021/om000054h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 1, 4-dilithiotetraphenylbutadiene with indium bromide affords the organometallic complex (Et2O)(2)Li(Br)(2)In{(C4Ph4)}(2)In(Br)(2)Li(OEt2)(2) as yellow monoclinic crystals. The two 1,4-tetraphenylbutadienylene units are bridged by two indium atoms, affording a severely twisted In2C8 ten-membered ring.

引用

页码：1214 / 1215

页数：2

共 11 条

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