Trifluoromethylation reactions with potassium trifluoromethanesulfinate under electrochemical oxidation

被引：107

作者：

Tommasino, JB ^{[1
]}

Brondex, A ^{[1
]}

Médebielle, M ^{[1
]}

Thomalla, M ^{[1
]}

Langlois, BR ^{[1
]}

Billard, T ^{[1
]}

机构：

[1] Univ Lyon 1, Lab Synth Electrosynth & Reactiv Compose, UMR CNRS UCBL 5622, F-69622 Villeurbanne, France

来源：

SYNLETT | 2002年 / 10期

关键词：

trifluoromethylation; potassium trifluoromethanesulfinate; electrolysis; fluorinated compounds; trifluoromethylated alkanes and alkenes; trifluoromethylated aromatics;

D O I：

10.1055/s-2002-34210

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrochemical oxidation of potassium trifluoromethanesulfinate (CF3SO2K) in the presence of electron-rich aromatics and alkenes provides the corresponding trifluoromethylated products.

引用

页码：1697 / 1699

页数：3

共 17 条

[1] [Anonymous], 1991, Fluorine in Bioorganic Chemistry
[2] Synthetic uses of thioesters of trifluoromethylated acids. Part 2. Reactions with alkenes
Billard, T
Roques, N
Langlois, BR
[J]. TETRAHEDRON LETTERS, 2000, 41 (17) : 3069 - 3072
[3] Synthetic uses of thio- and selenoesters of trifluoromethylated acids. 1. Preparation of trifluoromethyl sulfides and selenides
Billard, T
Roques, N
Langlois, BR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (11) : 3813 - 3820
[4] FILLER R, 1993, ORGANOFLUORINE MED C
[5] ELECTROCHEMICAL SYNTHESIS OF TRIFLUOROMETHANE SULFINIC ACID SALT FROM CF3BR AND SO2
FOLEST, JC
NEDELEC, JY
PERICHON, J
[J]. SYNTHETIC COMMUNICATIONS, 1988, 18 (13) : 1491 - 1494
[6] FORAT G, Patent No. 953515
[7] FOSSEY J, 1993, RADICAUX LIBRES CHIM, P73
[8] HUDLICKY M, 1995, ACS MONOGRAPH, V187
[9] TRIFLUOROMETHYLATION OF AROMATIC-COMPOUNDS WITH SODIUM TRIFLUOROMETHANESULFINATE UNDER OXIDATIVE CONDITIONS
LANGLOIS, BR
LAURENT, E
ROIDOT, N
[J]. TETRAHEDRON LETTERS, 1991, 32 (51) : 7525 - 7528
[10] LANGLOIS BR, 1992, TETRAHEDRON LETT, V33, P191

← 1 2 →