Infrared-to-visible Eu3+ energy upconversion due to cooperative energy transfer from an Yb3+ ion pair in a sol-gel processed multi-component silica glass

被引:104
作者
Maciel, GS [1 ]
Biswas, A [1 ]
Prasad, PN [1 ]
机构
[1] SUNY Buffalo, Photon Res Lab, Dept Chem, Buffalo, NY 14260 USA
关键词
upconversion; sol-gel silica glass; cooperative energy transfer;
D O I
10.1016/S0030-4018(00)00615-5
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Energy upconversion of Eu3+ is demonstrated in a sol-gel processed silica glass co-doped with Yb3+ ions. Yellow-range emission is observed originating from the Eu3+ ions due to nonresonant cooperative energy transfer from pairs of excited Yb3+ ions when a diode laser emitting at a wavelength of 973 nm is used as an excitation source. The Yb3+-Eu3+ energy transfer rate is estimated as similar to 280 s(-1) based on an analysis of the Yb3+ infrared luminescence decay time. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:65 / 69
页数:5
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