Preparation of poly (3,4-ethylenedioxythiophene) in a chiral nematic liquid-crystal field

被引：56

作者：

Goto, H ^{[1
]}

Akagi, K ^{[1
]}

机构：

[1] Univ Tsukuba, Inst Mat Sci, TIMS, Tsukuba, Ibaraki 3058573, Japan

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 16期

关键词：

chiral; conjugated polymers; liquid crystals; poly(3,4-ethylenedioxythiophene); SEM;

D O I：

10.1002/marc.200400184

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The 3,4-ethylenedioxythiophene (EDOT) monomer in a chiral nematic liquid-crystal electrolyte was polymerized by application of a voltage to yield a thin film. Circular dichroism measurements indicated a Cotton effect for the film. Optical texture suggests that the polymer shows a finger-print texture and a spiral texture similar to that of the chiral nematic phase. This simple method provides a new technique for preparing chiral conducting films in a thermotropic chiral liquid-crystal field.

引用

页码：1482 / 1486

页数：5

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