Dynamic properties of semidilute solutions at the theta point

被引:15
作者
Adam, M [1 ]
Lairez, D [1 ]
Raspaud, E [1 ]
Farago, B [1 ]
机构
[1] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE
关键词
D O I
10.1103/PhysRevLett.77.3673
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Here we report results obtained by neutron spin echo on semidilute theta solutions of polystyrene in deuterated cyclohexane. It is shown that the pertinent length for the diffusion coefficient is not the correlation length xi(theta) of concentration fluctuations but rather the distance between binary contacts. At length scales smaller than this distance, the dynamics is linked to the local viscosity, which is found to be surprisingly concentration and temperature dependent.
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页码:3673 / 3676
页数:4
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