Humidity sensitive properties of alkoxysilane-crosslinked polyelectrolyte using sol-gel process

被引:35
作者
Lee, CW
Choi, BK
Gong, MS [1 ]
机构
[1] Dankook Univ, Dept Chem, Cheonan 330714, Chungnam, South Korea
[2] Dankook Univ, Dept Appl Phys, Seoul 140714, South Korea
关键词
D O I
10.1039/b404334k
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
New trialkoxysilyl group-containing copolymers for humidity-sensitive polyelectrolytes were prepared by copolymerization of [2-(methacryloyloxy) ethyl] trimethyl ammonium chloride (METAC), 3-(trimethoxysilyl) propyl methacrylate (TSPM) and 2-ethylhexyl acrylate (2-EHA). They were self-crosslinkable copolymers composed of different contents of METAC/TSPM/2-EHA = 4/1/ 5 and 4/2/4. The resistance varied from 10(7) to 10(3) Omega between 20% RH and 95% RH, which was required for a humidity sensor operating at ambient humidity. Temperature dependence, hysteresis, response time, water durability and long-term stability at high temperature and humidity were also measured and estimated.
引用
收藏
页码:651 / 656
页数:6
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