Regioselective domino metathesis of 2-substituted 7-oxanorborn-5-enes

被引：11

作者：

Arjona, O ^{[1
]}

Csákÿ, AG ^{[1
]}

Murcia, MC ^{[1
]}

Plumet, J ^{[1
]}

机构：

[1] Univ Complutense, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain

来源：

ARKIVOC | 2002年

关键词：

regioselective; metathesis; 7-oxanorborn-5-ene; carbometallation;

D O I：

10.3998/ark.5550190.0003.519

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regiochemistry of the domino metathesis reaction of 2-endo substituted 7-oxanorbornenic allyl amines and allyl ethers have been studied. The results lead to two alternative reaction pathways, starting either by ring-opening metathesis of the endocyclic C=C bond or by carbometallation of the C=C bond of the alkenyl chain.

引用

页码：171 / 180

页数：10

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