Highly Fluorescent Rigid Supramolecular Polymeric Nanowires Constructed Through Multiple Hydrogen Bonds

被引:83
作者
Luo, Jia [1 ,2 ]
Lei, Ting [1 ]
Wang, Lei [2 ]
Ma, Yuguo [1 ]
Cao, Yong [2 ]
Wang, Jian [2 ]
Pei, Jian [1 ]
机构
[1] Peking Univ, Beijing Natl Lab Mol Sci, Key Labs Bioorgan Chem & Mol Engn & Polymer Chem, Minist Educ, Beijing 100871, Peoples R China
[2] S China Univ Technol, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
TRANSISTORS;
D O I
10.1021/ja8090774
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Suprannolecular polymeric nanowires 1 nconstructed by a 3D shape-persistent hexaacid 1 through multiple hydrogen bonding interactions was developed. Single molecular nanoires were also obtained from its highly dilute solution.Hexaacid 1 containing pi-conjugated chromophores successfully self-assembled to afford these nanofibers with high solid quantum efficiency (22%), which provides us a pathway to fabricate optoelectronic devices using these highly fluorescent nanofibers.
引用
收藏
页码:2076 / +
页数:3
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