Hydriding of Mg2Ni in ammonia

被引:3
作者
Fokin, V. N. [1 ]
Fokina, E. E. [1 ]
Tarasov, B. P. [1 ]
机构
[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
关键词
HYDROGEN STORAGE; MAGNESIUM; SYSTEM;
D O I
10.1134/S0020168509080068
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The chemical interaction between the intermetallic compound Mg2Ni and ammonia in the presence of NH4Cl as an activator is investigated at temperatures from 100 to 450 A degrees C, and the reaction scheme is presented. The results demonstrate that the use of ammonia for hydriding/nitriding the intermetallic compound makes it possible to prepare various magnesium compounds (Mg2NiH4, Mg3N2, and Mg (NH2)(2)) in a highly dispersed state.
引用
收藏
页码:859 / 862
页数:4
相关论文
共 12 条
[1]  
Fokin V. N., 2008, IAN SSSR NEORG MATER, V44, P184
[2]  
FOKIN VN, 2008, ALTERN ENERG EKOL, P19
[3]  
Klyamkin S.N., 2006, Ross. Chim. Zhurnal, V50, P49
[4]  
LYAKISHEV NP, 2001, DIAGRAMMY SOSTOYANIY, V2
[5]   KINETICS OF THE REACTION BETWEEN MG2NI AND HYDROGEN [J].
NOMURA, K ;
AKIBA, E ;
ONO, S .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1981, 6 (03) :295-303
[6]   REACTION HYDROGEN WITH ALLOYS MAGNESIUM AND NICKEL AND FORMATION OF MG2NIH4 [J].
REILLY, JJ ;
WISWALL, RH .
INORGANIC CHEMISTRY, 1968, 7 (11) :2254-&
[7]  
SEMENENKO KN, 1984, ZH NEORG KHIM+, V29, P2192
[8]   Microstructure and hydrogen storage properties of the laser sintered Mg2Ni alloy [J].
Si, T. Z. ;
Liu, D. M. ;
Zhang, Q. A. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (18) :4912-4916
[9]   Pressure-composition isotherms in the Mg2Ni-H2 system [J].
Song, MY ;
Park, HR .
JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 270 (1-2) :164-167
[10]  
TARASOV BP, 2004, ALTERNATIVNAYA ENERG, P58