pH-Sensitive locomotion of cycloclextrins in a block-selective mobile polyrotaxane

被引：20

作者：

Choi, Hak Soo

Hirasawa, Ayaka

Ooya, Tooru

Kajihara, Daisuke

Hohsaka, Takahiro

Yui, Nobuhiko

机构：

[1] Sch Mat Sci, Nomi, Ishikawa 9231292, Japan

[2] Japan Adv Inst Sci & Technol, Century COE Program 21, Nomi, Ishikawa 9231292, Japan

来源：

CHEMPHYSCHEM | 2006年 / 7卷 / 08期

关键词：

cyclodextrins; FRET (fluorescence resonant energy transfer); NMR spectroscopy; polyrotaxane; supramolecular chemistry;

D O I：

10.1002/cphc.200600242

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

(Figure Presented) On the move! A block-selective mobile polyrotaxane, synthesized in a one-pot sequence using anthracene (AN) capping agents, examines the movement of α-cyclodextrins (α-CDs) along the chains of a PEI-b-PEG-6-PEI copolymer (see figure). By labeling the α-CDs with fluorescein (FL) and monitoring the fluorescence resonance energy transfer, the intramolecular block-selective movement of α-CDs is characterized in response to pH variation. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

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页码：1671 / 1673

页数：3

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