Optically active ruthenium porphyrins: chiral recognition and asymmetric catalysis

被引：157

作者：

Simonneaux, G ^{[1
]}

Le Maux, P ^{[1
]}

机构：

[1] Univ Rennes 1, UMR 6509, Lab Chim Organomet & Biol, F-35042 Rennes, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2002年 / 228卷 / 01期

关键词：

ruthenium; optically active porphyrins; chiral recognition; asymmetric catalysis;

D O I：

10.1016/S0010-8545(02)00009-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The current applications of ruthenium porphyrins in stoichiometric and catalytic asymmetric reactions are reported. Chiral recognition of racemic phosphines, isocyanides and amino esters has been studied by H-1-NMR. Experimental investigations of the oxidation mechanism of racemic phosphines and amino esters are described. The stereochemistry of catalytic asymmetric oxidation and cyclopropanation of olefins with optically active ruthenium porphyrins are also discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：43 / 60

页数：18

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