Modification of semiconductor surface with ultrafine metal particles for efficient photoelectrochemical reduction of carbon dioxide

被引:32
作者
Hinogami, R
Nakamura, Y
Yae, S
Nakato, Y
机构
[1] OSAKA UNIV,GRAD SCH ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN
[2] OSAKA UNIV,RES CTR PHOTOENERGET ORGAN MAT,TOYONAKA,OSAKA 560,JAPAN
关键词
silicon; solar energy conversion; ideal semiconductor electrode; nanometer control;
D O I
10.1016/S0169-4332(97)00310-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A p-type silicon (p-Si) electrode modified with small metal (Cu, Au and Ag) particles works as an ideal-type electrode for photoelectrochemical reduction of carbon dioxide, producing carbon monoxide, methane, ethylene, etc., with a large photovoltage of 0.5 V. It is discussed that two types of surface-structure control on atomic and nanometer-sized levels are important for getting a high efficiency. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:301 / 304
页数:4
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