Using a molten organic conducting material to infiltrate a nanoporous semiconductor film and its use in solid-state dye-sensitized solar cells

被引:26
作者
Fredin, Kristofer [2 ,4 ]
Johansson, Erik M. J. [1 ]
Blom, Tobias [3 ]
Hedlund, Maria [2 ]
Plogmaker, Stefan [2 ]
Siegbahn, Hans [2 ]
Leifer, Klaus [3 ]
Rensmo, Hakan [2 ]
机构
[1] Lund Univ, Dept Chem Phys, SE-22100 Lund, Sweden
[2] Uppsala Univ, Dept Phys & Mat Sci, SE-75121 Uppsala, Sweden
[3] Uppsala Univ, Dept Engn Sci, SE-75121 Uppsala, Sweden
[4] Lund Univ, Max Lab, SE-22363 Lund, Sweden
基金
瑞典研究理事会;
关键词
TiO2; Dye; Nanoporous; Hole-conductor; Triarylamine; HOLE CONDUCTOR; INTERFACIAL PROPERTIES; TIO2; FILMS; EFFICIENCY; CONVERSION; HETEROJUNCTIONS;
D O I
10.1016/j.synthmet.2008.06.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We describe a method to fill thin films of nanoporous TiO2 with solid organic hole-conducting materials and demonstrate the procedure specifically for use in the preparation of dye-sensitized solar cells. Cross-sections of the films were investigated by scanning electron microscopy and it was observed that a hot molten organic material fills pores that are 10 mu m below the surface of the film. We characterized the incident photon to current conversion efficiency properties of the solid TiO2/organic dye/organic hole-conductor heterojunctions and the spectra show that the dye is still active after the melting process. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:166 / 170
页数:5
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