Asymmetric cleavage of chiral alpha,beta-ethylenic acetals by organolithium reagents

被引：8

作者：

Alexakis, A

Mhamdi, F

Lagasse, F

Mangeney, P

机构：

[1] Lab. de Chim. des Organo-Elements, CNRS UA 473, case 183 Univ. P. et M. Curie, F-75252 Paris Cedex 05, 4, Place Jussieu

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(96)00438-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

alpha,beta-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyzed into a chiral beta-disubstituted aldehyde. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：3343 / 3346

页数：4

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