Determination of activation energies by using different factors Φ in adiabatic calorimetry

被引：16

作者：

Sempere, J

Nomen, R

Serra, R

Gallice, F

机构：

[1] Univ Ramon Llull, Inst Quim Sarrir, Dept Chem Engn, E-08017 Barcelona, Spain

[2] Sanofi Chim, F-30390 Aramon, France

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1999年 / 58卷 / 01期

关键词：

adiabatic calorimetry; kinetics; Kissinger method;

D O I：

10.1023/A:1010105702893

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Traditionally, the kinetic treatment of adiabatic calorimetry data has been based on the results of one or more experiments, but always with the assumption of the kinetic model that the reaction follows to calculate the kinetic parameters. In this paper a method for the determination of the activation energy that uses a set of adiabatic calorimetry data is developed. To check the method, the thermal decompositions of two peroxides were studied.

引用

页码：215 / 223

页数：9