Crystal structure and reversible O2-binding of a room temperature stable μ-η2:η2-peroxodicopper(II) complex of a sterically hindered hexapyridine dinucleating ligand

被引:129
作者
Kodera, M [1 ]
Katayama, K
Tachi, Y
Kano, K
Hirota, S
Fujinami, S
Suzuki, M
机构
[1] Doshisha Univ, Dept Mol Sci & Technol, Kyoto 6100321, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 46401, Japan
[3] Kanazawa Univ, Dept Chem, Kanazawa, Ishikawa 9201192, Japan
关键词
D O I
10.1021/ja992295q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:11006 / 11007
页数:2
相关论文
共 35 条
[1]   SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].
ADDISON, AW ;
RAO, TN ;
REEDIJK, J ;
VANRIJN, J ;
VERSCHOOR, GC .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356
[2]   SPECTROSCOPIC STUDIES OF SIDE-ON PEROXIDE-BRIDGED BINUCLEAR COPPER(II) MODEL COMPLEXES OF RELEVANCE TO OXYHEMOCYANIN AND OXYTYROSINASE [J].
BALDWIN, MJ ;
ROOT, DE ;
PATE, JE ;
FUJISAWA, K ;
KITAJIMA, N ;
SOLOMON, EI .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (26) :10421-10431
[3]   Intramolecular ligand hydroxylation:: Mechanistic high-pressure studies on the reaction of a dinuclear copper(I) complex with dioxygen [J].
Becker, M ;
Schindler, S ;
Karlin, KD ;
Kaden, TA ;
Kaderli, S ;
Palanché, T ;
Zuberbühler, AD .
INORGANIC CHEMISTRY, 1999, 38 (09) :1989-1995
[4]   Dioxygen binding at ambient temperature: Formation of a novel peroxodicopper(II) complex with an azole macrocyclic ligand [J].
Bol, JE ;
Driessen, WL ;
Ho, RYN ;
Maase, B ;
Que, L ;
Reedijk, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (09) :998-1000
[5]  
BOZEL H, 1999, CHEM-EUR J, V5, P1716
[6]   Novel heterocyclic betaines relevant to the mechanism of tyrosinase-catalysed oxidation of phenols [J].
Clews, J ;
Cooksey, CJ ;
Garratt, PJ ;
Land, EJ ;
Ramsden, CA ;
Riley, PA .
CHEMICAL COMMUNICATIONS, 1998, (01) :77-78
[7]   Evidence of the indirect formation of the catecholic intermediate substrate responsible for the autoactivation kinetics of tyrosinase [J].
Cooksey, CJ ;
Garratt, PJ ;
Land, EJ ;
Pavel, S ;
Ramsden, CA ;
Riley, PA ;
Smit, NPM .
JOURNAL OF BIOLOGICAL CHEMISTRY, 1997, 272 (42) :26226-26235
[8]   Crystal structure of a functional unit from Octopus hemocyanin [J].
Cuff, ME ;
Miller, KI ;
van Holde, KE ;
Hendrickson, WA .
JOURNAL OF MOLECULAR BIOLOGY, 1998, 278 (04) :855-870
[9]   Structural and functional aspects of metal sites in biology [J].
Holm, RH ;
Kennepohl, P ;
Solomon, EI .
CHEMICAL REVIEWS, 1996, 96 (07) :2239-2314
[10]   Mechanistic studies of aliphatic ligand hydroxylation of a copper complex by dioxygen: A model reaction for copper monooxygenases [J].
Itoh, S ;
Nakao, H ;
Berreau, LM ;
Kondo, T ;
Komatsu, M ;
Fukuzumi, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (12) :2890-2899