Synthesis and nonlinear optical properties of 1,3,5-methoxy-2,4,6-tris(styryl)benzene derivatives

被引:45
作者
Cho, BR
Chajara, K
Oh, HJ
Son, KH
Jeon, SJ
机构
[1] Korea Univ, Dept Chem, Mol Opto Elect Lab, Seoul 136701, South Korea
[2] Korea Univ, Dept Chem, Ctr Elect Photo Respons Mol, Seoul 136701, South Korea
关键词
D O I
10.1021/ol025739n
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Novel two-dimensional octupoles containing donors at the core and acceptors at the edge of peripheral groups were synthesized by Horner-Wittig reactions. These chromophores show very large first hyperpolarizability and good thermal stability and are attractive candidates for nonlinear optical materials.
引用
收藏
页码:1703 / 1706
页数:4
相关论文
共 28 条
  • [1] Multipolar molecules and multipolar fields: probing and controlling the tensorial nature of nonlinear molecular media
    Brasselet, S
    Zyss, J
    [J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1998, 15 (01) : 257 - 288
  • [2] Propeller-shaped molecules with giant off-resonance optical nonlinearities
    Brunel, J
    Ledoux, I
    Zyss, J
    Blanchard-Desce, M
    [J]. CHEMICAL COMMUNICATIONS, 2001, (10) : 923 - 924
  • [3] First order hyperpolarizabilities of 2-[2-(p-diethylaminophenyl)vinyl]furan derivatives
    Cho, BR
    Son, KN
    Lee, SJ
    Kang, TI
    Han, MS
    Jeon, SJ
    Song, NW
    Kim, D
    [J]. TETRAHEDRON LETTERS, 1998, 39 (20) : 3167 - 3170
  • [4] Octupolar crystals for nonlinear optics: 1,3,5-trinitro-2,4,6-tris(styryl)benzene derivatives
    Cho, BR
    Lee, SJ
    Lee, SH
    Son, KH
    Kim, YH
    Doo, JY
    Lee, GJ
    Kang, TI
    Lee, YK
    Cho, MH
    Jeon, SJ
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (05) : 1438 - +
  • [5] 1,3,5-tricyano-2,4,6-tris(vinyl)benzene derivatives with large second-order nonlinear optical properties
    Cho, BR
    Park, SB
    Lee, SJ
    Son, KH
    Lee, SH
    Lee, MJ
    Yoo, J
    Lee, YK
    Lee, GJ
    Kang, TI
    Cho, MH
    Jeon, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (26) : 6421 - 6422
  • [6] From molecules to opto-chips: organic electro-optic materials
    Dalton, LR
    Steier, WH
    Robinson, BH
    Zhang, C
    Ren, A
    Garner, S
    Chen, AT
    Londergan, T
    Irwin, L
    Carlson, B
    Fifield, L
    Phelan, G
    Kincaid, C
    Amend, J
    Jen, A
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) : 1905 - 1920
  • [7] Synthesis and nonlinear optical, photophysical, and electrochemical properties of subphthalocyanines
    del Rey, B
    Keller, U
    Torres, T
    Rojo, G
    Agulló-López, F
    Nonell, S
    Martí, C
    Brasselet, S
    Ledoux, I
    Zyss, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (49) : 12808 - 12817
  • [8] DHNAULT CJ, 1995, NATURE, V374, P339
  • [9] ELECTROCHROMISM OF SUBSTITUTED POLYALKENES IN POLYMER MATRICES - INFLUENCE OF CHAIN-LENGTH ON CHARGE-TRANSFER
    HAVINGA, EE
    VANPELT, P
    [J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1979, 83 (08): : 816 - 821
  • [10] Hyper-Rayleigh Scattering in isotropic solution
    Hendrickx, E
    Clays, K
    Persoons, A
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (10) : 675 - 683