Shuttle suppression in room temperature sodium-sulfur batteries using ion selective polymer membranes

被引：158

作者：

Bauer, I. ^{[1
]}

Kohl, M. ^{[1
]}

Althues, H. ^{[1
]}

Kaskel, S. ^{[1
]}

机构：

[1] Fraunhofer Inst Mat & Beam Technol IWS, D-01277 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 24期

关键词：

POLYSULFIDE SHUTTLE; LITHIUM; CATHODE; CELL;

D O I：

10.1039/c4cc00161c

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A sodiated Nafion-coating on a porous polypropylene backbone was used as a cation selective separator for room temperature sodium-sulfur batteries. The capacity of the cells after 20 cycles could be enhanced by 75% to 350 mA h g(sulfur)(-1) using the new separator.

引用

页码：3208 / 3210

页数：3

共 27 条

[1]

Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[2]

Reduced polysulfide shuttle in lithium-sulfur batteries using Nafion-based separators [J].

Bauer, I. ;

Thieme, S. ;

Brueckner, J. ;

Althues, H. ;

Kaskel, S. .

JOURNAL OF POWER SOURCES, 2014, 251 :417-422

[3]

Berthelot R, 2011, NAT MATER, V10, P74, DOI [10.1038/nmat2920, 10.1038/NMAT2920]

[4]

Bito A, 2005, IEEE POWER ENG SOC, P1232

[5]

Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]

[6]

Carbon- Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability [J].

Brueckner, Jan ;

Thieme, Soeren ;

Boettger-Hiller, Falko ;

Bauer, Ingolf ;

Grossmann, Hannah Tamara ;

Strubel, Patrick ;

Althues, Holger ;

Spange, Stefan ;

Kaskel, Stefan .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (09) :1284-1289

[7]

Sodium-ion batteries using ion exchange membranes as electrolytes and separators [J].

Cao, Chengying ;

Liu, Weiwei ;

Tan, Lei ;

Liao, Xiaozhen ;

Li, Lei .

CHEMICAL COMMUNICATIONS, 2013, 49 (100) :11740-11742

[8]

Hartmann P, 2013, NAT MATER, V12, P228, DOI [10.1038/nmat3486, 10.1038/NMAT3486]

[9]

Moving to a Solid-State Configuration: A Valid Approach to Making Lithium-Sulfur Batteries Viable for Practical Applications [J].

Hassoun, Jusef ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2010, 22 (45) :5198-+

[10]

Holleman A. F., 2007, LEHRBUCH ANORGANISCH

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