Rovibrational motion of CO in solid C-60

被引：52

作者：

Holleman, I ^{[1
]}

von Helden, G ^{[1
]}

Olthof, EHT ^{[1
]}

vanBentum, PJM ^{[1
]}

Engeln, R ^{[1
]}

Nachtegaal, GH ^{[1
]}

Kentgens, APM ^{[1
]}

Meier, BH ^{[1
]}

vanderAvoird, A ^{[1
]}

Meijer, G ^{[1
]}

机构：

[1] CATHOLIC UNIV NIJMEGEN, NIJMEGEN SON RES CTR, NL-6525 ED NIJMEGEN, NETHERLANDS

来源：

PHYSICAL REVIEW LETTERS | 1997年 / 79卷 / 06期

关键词：

D O I：

10.1103/PhysRevLett.79.1138

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Solid C-60 can be intercalated with CO gas in a 1:1 ratio. The rovibrational motion of CO in these samples is studied as a function of temperature by IR and NMR spectroscopy. The observed spectra indicate a gradual transition from nearly free motion of CO at room temperature to hindered motion at low temperature, with only tunneling between symmetry equivalent orientations remaining. The observations are augmented by theory, and details on the local environment of the CO molecules are extracted.

引用

页码：1138 / 1141

页数：4

共 19 条

[1] INTERCALATION OF MOLECULAR-SPECIES INTO THE INTERSTITIAL SITES OF FULLERENE
ASSINK, RA
SCHIRBER, JE
LOY, DA
MOROSIN, B
CARLSON, GA
[J]. JOURNAL OF MATERIALS RESEARCH, 1992, 7 (08) : 2136 - 2143
[2] LOW-TEMPERATURE C-13 MAGNETIC-RESONANCE IN SOLIDS .3. LINEAR AND PSEUDOLINEAR MOLECULES
BEELER, AJ
ORENDT, AM
GRANT, DM
CUTTS, PW
MICHL, J
ZILM, KW
DOWNING, JW
FACELLI, JC
SCHINDLER, MS
KUTZELNIGG, W
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (25) : 7672 - 7676
[3] INTERCALATION OF O2 IN SOLID C60 AND MOLECULAR-ROTATION HINDRANCE
BELAHMER, Z
BERNIER, P
FIRLEJ, L
LAMBERT, JM
RIBET, M
[J]. PHYSICAL REVIEW B, 1993, 47 (23): : 15980 - 15983
[4] ENDOHEDRAL FULLERITES - A NEW CLASS OF FERROELECTRIC MATERIALS
CIOSLOWSKI, J
NANAYAKKARA, A
[J]. PHYSICAL REVIEW LETTERS, 1992, 69 (19) : 2871 - 2873
[5] STRUCTURAL PHASE-TRANSITIONS IN THE FULLERENE C-60
DAVID, WIF
IBBERSON, RM
DENNIS, TJS
HARE, JP
PRASSIDES, K
[J]. EUROPHYSICS LETTERS, 1992, 18 (03): : 219 - 225
[6] Storage of hydrogen in single-walled carbon nanotubes
Dillon, AC
Jones, KM
Bekkedahl, TA
Kiang, CH
Bethune, DS
Heben, MJ
[J]. NATURE, 1997, 386 (6623) : 377 - 379
[7] Neutron irradiation of Ar1C60
Gadd, GE
Evans, PJ
Hurwood, DJ
Wood, J
Moricca, S
Blackford, M
Elcombe, M
Kennedy, S
James, M
[J]. CHEMICAL PHYSICS LETTERS, 1996, 261 (03) : 221 - 227
[8] ANISOTROPY OF CHEMICAL-SHIFT TENSOR FOR SOLID CARBON-MONOXIDE
GIBSON, AAV
SCOTT, TA
FUKUSHIMA, E
[J]. JOURNAL OF MAGNETIC RESONANCE, 1977, 27 (01) : 29 - 33
[9] STRUCTURE, DYNAMICS AND ORDERING TRANSITION OF SOLID C-60
HEINEY, PA
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1992, 53 (11) : 1333 - 1352
[10] ORIENTATIONAL ORDERING TRANSITION IN SOLID C60
HEINEY, PA
FISCHER, JE
MCGHIE, AR
ROMANOW, WJ
DENENSTEIN, AM
MCCAULEY, JP
SMITH, AB
COX, DE
[J]. PHYSICAL REVIEW LETTERS, 1991, 66 (22) : 2911 - 2914

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