Manganese(III)-catalysed oxidation of sulphides with sodium chlorite in an aprotic solvent in the presence of alumina

被引：41

作者：

Hirano, M

Yakabe, S

Clark, JH

Kudo, H

Morimoto, T

机构：

[1] UNIV YORK, DEPT CHEM, YORK YO1 5DD, N YORKSHIRE, ENGLAND

[2] TOKYO UNIV AGR & TECHNOL, FAC TECHNOL, DEPT APPL CHEM, KOGANEI, TOKYO 184, JAPAN

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 10期

关键词：

D O I：

10.1080/00397919608003540

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A wide variety of sulphides can be readily converted to the corresponding sulphoxides in good to excellent yields by treatment with a combination of sodium chlorite, (salen)manganese(III) complex, and chromatographic alumina in dichloromethane under mild and neutral conditions.

引用

页码：1875 / 1886

页数：12

共 34 条

[1] ARORA CS, 1983, CHEM IND-LONDON, P318
[2] SIMPLE AND FACILE OXIDATION OF ALDEHYDES TO CARBOXYLIC-ACIDS
BABU, BR
BALASUBRAMANIAM, KK
[J]. ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1994, 26 (01) : 123 - 125
[3] OXIDATION OF ALPHA,BETA-UNSATURATED ALDEHYDES
BAL, BS
CHILDERS, WE
PINNICK, HW
[J]. TETRAHEDRON, 1981, 37 (11) : 2091 - 2096
[4] Clark J.H., 1994, CATALYSIS ORGANIC RE
[5] CLARK JH, 1992, SUPPORTED REAGENTS P
[6] ACETOGENIN SYNTHESIS - ORGANOCOPPER REAGENTS, ANIONS OF 1,3-DITHIANS AND OF PROTECTED CYANOHYDRINS AS INTERMEDIATES IN KETIDE SIDE-CHAIN SYNTHESIS
COLOMBO, L
GENNARI, C
SANTANDREA, M
NARISANO, E
SCOLASTICO, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1980, (01): : 136 - 140
[7] SELECTIVE OXIDATION OF ALDEHYDES TO CARBOXYLIC-ACIDS WITH SODIUM-CHLORITE HYDROGEN-PEROXIDE
DALCANALE, E
MONTANARI, F
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (04) : 567 - 569
[8] A PRACTICAL, HIGHLY ENANTIOSELECTIVE SYNTHESIS OF THE TAXOL SIDE-CHAIN VIA ASYMMETRIC CATALYSIS
DENG, L
JACOBSEN, EN
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (15) : 4320 - 4323
[9] FLOOR M, 1989, RECL TRAV CHIM PAY B, V108, P384
[10] HAINES AH, 1984, FIESER FIESERS REAGE, V11, P482

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